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The dependence of the local environment of copper and cobalt ions in aqueous solutions, depending on the acidity of the solution

Abstract

The dependence of the local environment of copper and cobalt ions in aqueous solutions, depending on the acidity of the solution

Soldatov M.A., Chaynikov A.P., Kremennaya M.A.

Incoming article date: 15.12.2014

A study of X-ray absorption spectra depending solution of copper (II) and cobalt from the time of preparation of these solutions (immediately prior to the measurement and aged for six months), as well as the dependence of the spectra on the acidity of the solution (different levels of pH 5.7 and 1, which is achieved by addition of hydrochloric acid). Processing of the experimental spectra were in the software package Athena. The study established according to the experimental X-ray absorption spectra of the solution of copper (II) and cobalt chloride on the test conditions.

Keywords: X-ray absorption spectroscopy, soft X-rays, copper chloride, copper (II), cobalt chloride aqueous solution, X-ray absorption spectrometer Rigaku R-XAS, a cell with kapton window