Academician Oleg Figovsky is the founder of the Israeli research center "Polimate", as well as scientific Director R&D of companies "Polimate" and the NTI / HCT (USA). He has more than 500 inventions. The article briefly describes the most important patents received in the last 20 years in areas such as materials science, nanotechnology, building construction.
Keywords: non-isocyanate polyurethanes, nanotechnology, polymer concretes, hybrid materials, constructions
Compositions of receiving and using waterborne epoxy - NIPU coating were developed. Experiments to study the compatibility of components in the waterborne epoxy - NIPU coatings were carried out . The optimum ratio of the components of the composition, in order to obtain the necessary physical and mechanical properties of the coating was determinate. The optimal compositions were recommended for industrial application.
Keywords: coating, epoxy & nonisocyanate polyurethane, waterborne system, physical and mechanical properties
Cured linear hybrid epoxy-amine hydroxyurethane-grafted polymer are preparedby novel structure with lengthy epoxy-amine chains, pendulous hydroxyurethane units and a controlled number of cross-links. These hybrid polymers combine increased flexibility with well balanced physical-mechanical and physical-chemical properties of conventional epoxy-amine systems and may be used, for example, for manufacturing of synthetic/artificial leather and sport monolithic floorings. US Patent Application 14/296,478, filed June 05, 2014.
Keywords: linear epoxy-amine chains, hybrid hydroxyurethane-grafted polymers, synthetic nonisocyanate leather.
Recent advances in chemistry and technology of nonisocyanate polyurethane (NIPU) materials based on cyclic carbonate oligomers are reviewed in this paper. Reaction of the cyclic carbonate and amino groups results in β-hydroxyurethane fragments with specific properties. Primary attention is given to the hybrid materials that contain epoxy and acrylic compounds, especially materials based on renewable raw materials. Hybrid organic composites comprising of silanes are also considered. An overview of the recent publications in this field is provided with a more detailed description of achievements by the authors and their corporate employees. The use of NIPU materials as coatings, adhesives, and foams is described.
Keywords: nonisocyanate polyurethanes, cyclic carbonate oligomers, hybrid polymers
Recent advances in chemistry and technology of nonisocyanate polyurethane (NIPU) materials based on cyclic carbonate oligomers are reviewed in this paper. Reaction of the cyclic carbonate and amino groups results in β-hydroxyurethane fragments with specific properties. Primary attention is given to the hybrid materials that contain epoxy and acrylic compounds, especially materials based on renewable raw materials. Hybrid organic composites comprising of silanes are also considered. An overview of the recent publications in this field is provided with a more detailed description of achievements by the authors and their corporate employees. The use of NIPU materials as coatings, adhesives, and foams is described.
Keywords: nonisocyanate polyurethanes, cyclic carbonate oligomers, hybrid polymers
In the article is given a review on production and application nonisocyanate polyurethanes based on cyclic carbonate oligomers. Nonisocyanate polyurethane (NIPU) networks are obtained by reaction between the polycyclic carbonate oligomers and aliphatic or cycloaliphatic polyamines with primary amino groups. This forms a crosslinked polymer with β-hydroxyurethane groups of different structure – polyhydroxyurethane polymer. Considered as a proper NIPU and hybrid polymers, involving various other oligomeric systems (HNIPU). Significant attention was paid to the materials based on renewable raw materials.The authors give an overview of recent publications in the field with a more detailed description of the Polymate Ltd. achievements.
Keywords: nonisocyanate polyurethanes, cyclic carbonates, polyhydroxyurethane polymer.
In this article is reviewed the nature of organic hybrid nanocomposites. Promising directions in the field of organic hybrid nanocomposite materials will be methods for the synthesis of multicomponent materials, as well as the type of "net net" and "host-guest". The fundamental problem with the chemistry and physics of nanocomposites is dependent "structure-property". Solving this problem will move from research materials to their purposeful design.
Keywords: nanocomposite sol-gel technology, synthesis, nanoparticles.
This article describes a method for producing two-component nonisocyanate insulating foams and technology of its spraying on the insulated surface. It describes the device, which, along with standard equipment, includes principally new design of components pre-mixing chamber. Constructive solutions described in the article will allow using the compositions which have different time and temperature of curing than conventional PU foams.
Keywords: Keywords: spray foams, insulating foams, nonisocyanate urethanes, pre-mixing chamber.
The properties of the water-soluble high-modulus silicate systems: based on alkali metal polysilicates called liquid glass and chain their transformation from lower to higher oligomers, with the subsequent formation of colloidal solutions - silica sol. The methods of preparation, properties and applications of water-soluble high-modulus silicate systems. The possibilities of their use as a binder and modifying agents for various nanostructured composite materials. The examples of promising areas of application of liquid glass and high modulus of aqueous solutions of silicates in construction and industry. In particular show the possibility of using liquid glass and aqueous solutions of silicates in the production of nanostructured silicate polymer. In space engineering for manufacturing water-destructed mandrels used in the manufacture of solid rocket motor casings and pressure vessels 'cocoon' of composite materials by winding. The application of the inorganic sol to obtain a nanocomposite ceramics and monolithic blocks of silicon oxide, which can be used in various fields of modern technology. The possibility of using silica sol as a binder for refractory ultra-lightweight shielding materials used to protect equipment from high impacts. The directions of development of the production of new acid-resistant materials and linings for protection of chemical equipment, parts and components operating in corrosive environments.
Keywords: Keywords: water glass, silicate polymer concrete, additives, silicates organic bases tetrafurfuriloksisilan, furfural alcohol, nanostructure composite materials, water-soluble silicates, silica sol, sol-gel transition, cured xerogel water-destructed mandr