The solid solution of LiMn1/3Cr1/3Fe1/3O2 with the structure of α-NaFeO2 isostructural with the widely used LiCoO2 has been synthesized and investigated as a cathode material. Rated voltage of LiMn1/3Cr1/3Fe1/3O2 relative to the lithium is 4 V. The possibility of charging − discharging the material to a specific capacity of 220-250 mAh/g at currents of C/15-C/50 without phase transformations has been experimentally demonstrated.
Keywords: lithium-ion batteries, cathode materials, Delafosse, solid solution, X-ray structural analysis, electrochemical properties
The results of calculations on the stability of slope lands treated in a new way. Device intrasoil walls combined with loosened intervals allows prevent subsurface runoff water, which reduces surface erosion slopes, improves the fertility of farmland returns a highly eroded areas in turn, eliminates the wetlands at the foot of the slopes. Established that the stability of the treated soil layer on the slope ample.
Keywords: stability of sloping land, subsurface walls, soil subsurface runoff, soil erosion, wetlands, deep tillage, moisture saturation slope.
Some aspects of the use of fuzzy logic to generate a mathematical model to search for objects on the sea. Describes how to use the algorithm Mamdani, to create a model of fuzzy inference. Section gives an example of the use of Fuzzy Logic Toolbox package Matlab, for the simulation of fuzzy search engine and determine the optimal solution of the problem to find the object.
Keywords: mathematical model, fuzzy logic, object search algorithm Mamdani, membership function
We propose a method for constructing of algorithm of smooth management by the hydraulic actuator based on the method of combining the maximum principle. Such management increases the accuracy and non-failure operation of operation of the device
Keywords: the integrated principle of a maximum, management, the hydraulic actuator, synthesizing function, management synthesis, asynchronous variation
The combination of the unique, abnormal properties shown by oxidic systems with structure of spinel on the basis of transitional elements chromites draws attention of researchers for many years. Some systems on the basis of transitional elements chromites (for example, nickel and copper chromites) have critical elements (multicritical points, lines of phase transitions of the second sort, etc.) on the phase chart. Near these elements of the phase chart materials possess unique chemical and physical properties. Therefore development methods of receiving and research of phase forming and properties in NIO-CoO-CuO-Cr2O3 system represent fundamental and practical interest for chemistry and technology of inorganic substances. In this work processes of spinel structure formation in system 0,6 NiCr2O4 – 0,2 CoCr2O4 – 0,2 CuCr2O4 from crystal chemistry positions are considered. Formation of two solid solutions on the basis of nickel (II) chromite – with structure of cubic spinel and with tetragonal distorted structure is established. The influence of cooperative Yahn-Teller effect on processes of a spinel forming and on stabilizing impact of chloride of potassium on process of education of two spinel solid solutions is suggested. Influence of a power factor of cation stabilization in knots of a crystal lattice as one of the important factor in reaction of spinel structure formation is considered.
Keywords: spinels, chromites of transitional elements, Jahn-Teller effect
Article dedicated to design technologies of socio-cultural and ethno-political development of southern Russia. Proposed the concept of regional research programs.
Keywords: South Russia, Southern Federal University, technology, program, facility
Is presented the solution of important sectoral issues to improve traffic safety of rolling stock by reducing lateral wear of wheels and rails heads when changes trucks in curves parts of the route by increasing reliability and durability of the pivot site.
To resolve this task, the paper proposed to the original design decision metered supply of lubricant to the friction surfaces of the parts with wear and tear their contact surfaces. According to the proposed resolution on friction surfaces pivot site are hollow, filled with solid composite lubricant, which in process of deterioration will portions get in contact area.
Theoretical foundations and the equation of adaptive management is present.
Keywords: center plate, adaptive regulator, operating parameters, lubricating layer, wear
Fe-doped AlN nanorods were studied by means of x-ray absorption spectroscopy above the Fe K- and L2,3- edges. Theoretical simulations of the x-ray absorption spectra show that Fe atoms mainly substitute Al. A minor fraction of Fe interstitials or Fe-Al-N ternary alloy can be identified as well. Bader’s AIM analysis predicts that neutral substitutional FeAl defect is in 2+ charge state, though Al in pure AlN is in 3+ charge state. Fe L2,3 absorption spectra and photoluminescence data indicate the coexistence of Fe2+/Fe3+ in AlN:Fe nanorods so different charge states of substitutional FeAl should co-exist.
Keywords: diversification of management, production diversification, financial and economic purposes of a diversification, technological purposes of ensuring flexibility of production
In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.
Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT
This paper examines the effectiveness of the software framework developed by the authors for the task of sonar information systems software design. This is done by a theoretical estimate based on the data obtained during the actual production process, as well as practical by rebuilding the software using the skeleton. Fixed a set of indicators on which to judge the complexity and evaluated there . Finally, an assessment of the results of the experiment and draw conclusions about the direction of further research.
Keywords: software design, sonar information systems framework, performance evaluation
Production lines for manufacturing of cylindrical logs for wood construction are considered in the article. Technological factors influencing on efficiency of production lines are identified and classified. Results of research can be basis for improving production lines.
Keywords: Woodworking, cylindering, technological line, wood costraction, factors
This paper outlines the implementation of computer model of second-order visual mechanisms that are specific to spatial contrast modulations, and represents the results of testing the model. Computer simulation is based on "Filter-Rectify-Filter" model with some important additions. The inhibitory parts of receptive field of simulated mechanism are non-selective to orientation and spatial frequency of texture elements. Texture modulated by orientation or spatial frequency does not reduce flank inhibition and does not activate the mechanism. Unmodulated texture also does not cause activation of the filter because the flanking inhibition will be equal to or exceed the excitation. However, increasing the contrast in the center and reduction it on the flanks leads to the activation of the second order mechanism.
Keywords: Second order visual mechanisms, image filtering, texture, spatial modulation, computer simulation
The article describes peculiarities of modern syntax parser systems and problems originating in text analysis. As a result of comparative analysis the authors propose a unified approach to processing of unstructured texts in Russian and English which combines morphology and syntax processing. The developed syntax analysis system, using verbs’ valency dictionary, samples of minimal structural schemes of sentences and samples of conjunctions, allows choosing predicative structures of sentences in the text, realizing initial semantic analysis due to semantic content of predicate’s actants and building trees of syntactical subordination of sentences. The derived trees hold elements of tree of constitutives and tree of dependences. The proposed samples and rules organization allows resolving some of the problems of modern parsers. And the use of verbs’ valency dictionary allows reducing the number of sentences syntax analysis variants.
Keywords: automatic text processing; syntax parser; morphological analysis; structural text elements
In this paper a systematic study of individual single-walled and multi-walled carbon nanotubes was performed by Raman spectroscopy and high-resolution electron microscopy. We have presented the geometrical and electronic structure analysis on the examples of two tubes: individual single-walled and double-walled nanotubes. The role of different environmental effects and their influence on the final structure assignment are discussed. Moreover, we have shown that the Raman spectroscopy gives reliable estimations of the nanotube diameters and the conductivity. Given a non-destructible character of Raman spectroscopy, we may conclude that it is one of the most efficient methods for structure analysis of carbon nanotubes.
Keywords: Carbon nanotubes, Raman spectroscopy, electron microscopy
The paper considers different approaches and tools for system log files analysis. Authors describe typical cases where such analysis is required. Requirements for a multipurpose log analysis tool are stated. Three classes of log analysis tools are discussed: specialized ones, real-time analysis tools and configurable analyzers. Advantages and disadvantages of these tools are summarized. Reviewed tools are assessed in the terms of compliance to the stated requirements. Configurable analyzers are considered to be the most suitable tools for described tasks.
Keywords: system logs, semistructed form, pattern, structure recognition, records filtration